make a deposit from exchange wallet, then copy the address ( not qr) copy the characters , then go to web3 wallet hit send and paste ur address.

In my Binance account, two wallets are showing, as is usually the case. I can easily withdraw and deposit funds from the exchange wallet, but I cannot withdraw money from the wallet on the left side. What is the reason for this, and what will be the method to withdraw funds from that wallet? Please guide me.